Year of publication
2023
Journal
ACS Sustainable Chemistry & Engineering
Volume
11
Starting page
16661
Ending page
16668
The development of high-performance CO2 electrolyzers is crucial for accelerating the sustainable production of fuels and chemicals integrated with renewable energy sources. Here, we introduce a methodology to actively control mass transport inside a realistic zero-gap membrane electrode assembly of a CO2 electrolyzer by varying the gasket thickness, which consequently changes the cell compression. This allows control over the thickness and porosity of the gas diffusion electrodes, influencing the overall electrolyzer performance, as demonstrated using Ag-deposited electrodes. At low operating voltages (
Keywords
carbon dioxide reduction, gas diffusion electrode, membrane electrode assembly, mass transport, porosity, electrochemistry, computational modeling, carbon conversion
Research Areas
Funding sources